Curable fiberglass binder comprising a polyacetal or polyketal

ABSTRACT

A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises an acid-catalyzed reaction product of an aldehyde or ketone with a multihydric alcohol. When heated, the composition forms polyacetal or polyketal that undergoes curing to form a water-insoluble resin binder which exhibits good adhesion to glass. In a preferred embodiment, maleic anhydride initially serves as a catalyst and subsequently enters into a cross-linking reaction during curing to form a poly(ester-acetal). Also, in a preferred embodiment, the fiberglass is in the form of building insulation. In other embodiments the product can be a microglass-based substrate for use in a printed circuit board, battery separator, filter stock, or reinforcement scrim.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The subject invention pertains to an improved binding composition foruse with fiberglass. More specifically, the invention pertains to animproved curable composition comprising a reaction product of analdehyde or ketone with a multihydric alcohol. When heated, thecomposition forms a polyacetal or polyketal that undergoes cross-linkingupon curing to form a water-insoluble resin binder which exhibits goodadhesion to glass. The cured binder of the present invention is usefulas a fully acceptable replacement for formaldehyde-based binders innon-woven fiberglass products.

2. Description of the Related Art

Fiberglass binders have a variety of uses ranging from stiffeningapplications where the binder is applied to woven or non-wovenfiberglass sheet goods and cured, producing a stiffer product;thermo-forming applications wherein the binder resin is applied to asheet or lofty fibrous product, following which it is dried andoptionally B-staged to form an intermediate but yet curable product; andto fully cured systems such as building insulation.

Fibrous glass insulation products generally comprise matted glass fibersbonded together by a cured thermoset polymeric material. Molten streamsof glass are drawn into fibers of random lengths and blown into aforming chamber where they are randomly deposited as a mat onto atraveling conveyor. The fibers, while in transit in the forming chamberand while still hot from the drawing operation, are sprayed with anaqueous binder. A phenol-formaldehyde binder has been used throughoutthe fibrous glass insulation industry. The residual heat from the glassfibers and the flow of air through the fibrous mat during the formingoperation are generally sufficient to volatilize water from the binder,thereby leaving the remaining components of the binder on the fibers asviscous or semi-viscous high solids liquid. The coated fibrous mat istransferred to a curing oven where heated air, for example, is blownthrough the mat to cure the binder and rigidly bond the glass fiberstogether.

Fiberglass binders used in the present sense should not be confused withmatrix resins which are an entirely different and non-analogous field ofart. While sometimes termed “binders”, matrix resins act to fill theentire interstitial space between fibers, resulting in a dense, fiberreinforced product where the matrix must translate the fiber strengthproperties to the composite, whereas “binder resins” as used herein arenot space-filling, but rather coat only the fibers, and particularly thejunctions of fibers. Fiberglass binders also cannot be equated withpaper or wood product “binders” where the adhesive properties aretailored to the chemical nature of the cellulosic substrates. Many suchresins are not suitable for use as fiberglass binders. One skilled inthe art of fiberglass binders would not look to cellulosic binders tosolve any of the known problems associated with fiberglass binders.

Binders useful in fiberglass insulation products generally require a lowviscosity in the uncured state, yet possess characteristics so as toform a rigid thermoset polymeric mat for the glass fibers when cured. Alow binder viscosity in the uncured state is required to allow the matto be sized correctly. Also, viscous binders commonly tend to be tackyor sticky and hence they lead to the accumulation of fiber on theforming chamber walls. This accumulated fiber may later fall onto themat causing dense areas and product problems. A binder which forms arigid matrix when cured is required so that a finished fiberglassthermal insulation product, when compressed for packaging and shipping,will recover to its as-made vertical dimension when installed in abuilding.

From among the many thermosetting polymers, numerous candidates forsuitable thermosetting fiberglass binder resins exist. However,binder-coated fiberglass products are often of the commodity type, andthus cost becomes a driving factor, generally ruling out resins such asthermosetting polyurethanes, epoxies, and others. Due to their excellentcost/performance ratio, the resins of choice in the past have beenphenol-formaldehyde resins. Phenol-formaldehyde resins can beeconomically produced, and can be extended with urea prior to use as abinder in many applications. Such urea-extended phenol-formaldehydebinders have been the mainstay of the fiberglass insulation industry foryears, for example.

Over the past several decades however, minimization of volatile organiccompound emissions (VOCs) and hazardous air pollutants (HAPS) both onthe part of the industry desiring to provide a cleaner environment, aswell as by Federal regulation, has led to extensive investigations intonot only reducing emissions from the current formaldehyde-based binders,but also into candidate replacement binders. For example, subtle changesin the ratios of phenol to formaldehyde in the preparation of the basicphenol-formaldehyde resole resins, changes in catalysts, and addition ofdifferent and multiple formaldehyde scavengers, has resulted inconsiderable improvement in emissions from phenol-formaldehyde bindersas compared with the binders previously used. However, with increasinglystringent Federal regulations, more and more attention has been paid toalternative binder systems which are free from formaldehyde.

One such candidate binder system employs polymers of acrylic acid as afirst component, and a polyol such as glycerine or a modestlyoxyalkylated glycerine as a curing or “crosslinking” component. Thepreparation and properties of such poly(acrylic acid)-based binders,including information relative to the VOC emissions, and a comparison ofbinder properties versus urea-formaldehyde binders is presented in“Formaldehyde-Free Crosslinking Binders For Non-Wovens,” Charles T.Arkins et al., TAPPI Journal, Vol. 78, No. 11, pages 161-168, November1995. The binders disclosed by the Arkins article appear to beB-stageable as well as being able to provide physical properties similarto those of urea/formaldehyde resins.

U.S. Pat. No. 5,340,868 discloses fiberglass insulation products curedwith a combination of a polycarboxy polymer, α-hydroxyalkylamide, and atleast one trifunctional monomeric carboxylic acid such as citric acid.The specific polycarboxy polymers disclosed are poly(acrylic acid)polymers. See also, U.S. Pat. No. 5,143,582.

U.S. Pat. No. 5,318,990 discloses a fibrous glass binder which comprisesa polycarboxy polymer, a monomeric trihydric alcohol and a catalystcomprising an alkali metal salt of a phosphorous-containing organicacid.

Published European Patent Application EP 0 583 086 A1 appears to providedetails of polyacrylic acid binders whose cure is catalyzed by aphosphorus-containing catalyst system as discussed in the Arkins articlepreviously cited. Higher molecular weight poly(acrylic acids) are statedto provide polymers exhibiting more complete cure. See also U.S. Pat.Nos. 5,661,213; 5,427,587; 6,136,916; and 6,221,973.

Some polycarboxy polymers have been found useful for making fiberglassinsulation products. Problems of clumping or sticking of the glassfibers to the inside of the forming chambers during the processing, aswell as providing a final product that exhibits the recovery andrigidity necessary to provide a commercially acceptable fiberglassinsulation product, have been overcome. See, for example, U.S. Pat. No.6,331,350. The thermosetting acrylic resins have been found to be morehydrophilic than the traditional phenolic binders, however. Thishydrophilicity can result in fiberglass insulation that is more prone toabsorb liquid water, thereby possibly compromising the integrity of theproduct. Also, the thermosetting acrylic resins now being used asbinding agents for fiberglass have been found to not react aseffectively with silane coupling agents of the type traditionally usedby the industry. The addition of silicone as a hydrophobing agentresults in problems when abatement devices are used that are based onincineration. Also, the presence of silicone in the manufacturingprocess can interfere with the adhesion of certain facing substrates tothe finished fiberglass material. Overcoming these problems will help tobetter utilize polycarboxy polymers in fiberglass binders.

Accordingly, in one aspect, the present invention provides a novel,non-phenol-formaldehyde binder.

In another aspect, the invention provides a novel fiberglass binderwhich provides advantageous flow properties, the possibility of lowerbinder usage, the possibility of overall lower energy consumption,elimination of interference by a silane, and improved overall economics.

These and other aspects of the present invention will become apparent tothe skilled artisan upon a review of the following description and theclaims appended hereto.

SUMMARY OF THE INVENTION

A curable composition for use in the binding of fiberglass is providedcomprising an acid-catalyzed reaction product of an aldehyde or ketonewith a multihydric alcohol in the form of a polyacetal or polyketalwhich upon curing is capable of forming a water-insoluble resin binderwhich exhibits good adhesion to glass.

A process for binding fiberglass is contemplated comprising providing onfiberglass a coating of a composition comprising an acid-catalyzedreaction product of an aldehyde or ketone with a multihydric alcohol inthe form of a polyacetal or polyketal, and thereafter curing thecomposition while present as a coating on the fiberglass to form awater-insoluble resin binder which exhibits good adhesion to glass.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

The novel fiberglass binder composition is a curable compositioncomprising the acid-catalyzed reaction product of an aldehyde or ketonewith a multihydric alcohol in the form of a polyacetal or polyketalwhich upon curing is capable of forming a water-insoluble resin binderwhich exhibits good adhesion to glass.

In accordance with one embodiment, the reactants comprise an aldehydeand a multihydric alcohol and a polyacetal is formed, and in a preferredembodiment thereof the polyacetal is a poly(ester-acetal). The aldehydereactant can be a mono-aldehyde possessing a single aldehyde group or amulti-aldehyde possessing more than one aldehyde group. Representativemono-aldehydes include butyraldehyde, benzaldehyde, acrolein, acopolymer of acrolein with another unsaturated monomer, such as anacrylic acid, methacrylic acid, styrene, a vinyl monomer, and mixturesof these. Representative multi-aldehydes include glyoxal,glutaraldehyde, 1,5-pentanedial, 1,6-hexanedial, 1,4-terephthalicdianhydride, polyarolein, and mixtures of these. Preferredmulti-aldehydes are glyoxal and glutaraldehyde. The multi-aldehydes makepossible enhanced cross-linking in the cured reaction product.

Representative multihydric alcohols are ethylene glycol, 1,2-propyleneglycol, 1,3-propylene glycol, neopentyl glycol, pentaerythritol,glucose, sorbitol, polyvinyl alcohol, ethylene vinyl alcohol copolymer,and mixtures of these. A preferred multihydric alcohol is polyvinylalcohol.

In accordance with another embodiment, the reactants comprise a ketoneand a multihydric alcohol and a polyketal is formed. The ketone reactantcan contain one or more ketone group and the multihydric alcohol can beas described above when forming a polyacetal. When the ketone reactantincludes more than one ketone group, enhanced cross-linking is madepossible in the cured reaction product.

Representative ketone reactants include methylethyl ketone,methylisobutyl ketone, acetoquinone, cyclohexanedione, acetylacetone,benzophenone, polyketones, and mixtures of these. Preferred ketonereactants are methylisobutyl ketone and cyclohexanedione.

Suitable acids for use to catalyze the formation of the polyacetal orpolyketal reaction product include mineral acids, Lewis acids, andorganic acids. Representative acid catalysts include sulfuric acid,hydrochloric acid, sulfate salts, such as Al₂(SO₄)₃, bisulfite, such asNaHSO₃, FeCl₃, nitrate, such as NaNO₃, nitric acid, acetic acid, citricacid, glycolic acid, maleic acid, maleic anhydride, succinic acid,succinic anhydride, phthalic acid, polyacrylic acid, copolymers ofacrylic acid, polymethacrylic acid, copolymers of methacrylic acid,polymers of styrene and maleic anhydride, homo- and copolymers of maleicacid, homo- and copolymers of maleic anhydride, rosin, and modifiedrosins, etc. Sulfuric acid is a preferred catalyst.

In a particularly preferred embodiment, when forming either a polyacetalor polyketal reaction product the catalyst is maleic acid, maleicanhydride, succinic acid, or succinic anhydride. Such compounds catalyzethe initial formation of the polyacetal or polyketal and additionallyenter into a chemical reaction to form a more highly cross-linked finalreaction product. For instance, when the aldehyde and multihydricalcohol are reacted to form a polyacetal, and maleic acid is provided,the final polyacetal product possesses the chemical structure of apoly(ester-acetal).

The reactants can be applied to fiberglass as a coating while admixed inan aqueous medium. The composition when applied to the fiberglassoptionally can include adhesion prompters, oxygen scavengers, solvents,emulsifiers, pigments, fillers, anti-migration aids, coalescents,wetting agents, biocides, plasticizers, organosilanes, anti-foamingagents, colorants, waxes, suspending agents, anti-oxidants, crosslinkingcatalysts, secondary crosslinkers, and combinations of these.

The coating application can be achieved in accordance with knowntechniques for coating a fibrous web. In preferred embodiments, theseinclude spraying, spin-curtain coating, and dipping-roll coating. Thecomposition can be applied to freshly-formed fiberglass, or tofiberglass following collection.

In a preferred embodiment, the fiberglass is building insulation. Inother embodiments, the fiberglass is a microglass-based substrate usefulwhen forming a printed circuit board, battery separator, filter stock,or reinforcement scrim.

Once applied to the fiberglass, the coated product is heated at atemperature and time sufficient to achieve the formation of a polyacetalor polyketal that subsequently undergoes curing to form awater-insoluble resin binder which exhibits good adhesion to glass.During the curing, water is formed as a by-product and is removed byvolitization. Representative heating temperatures commonly areapproximately 80 to 250° C., e.g. 80 to 200° C.

The cured polyacetal or polyketal at the conclusion of the curing stepcommonly is present as a secure coating on the fiberglass in aconcentration of approximately 0.5 to 50 percent by weight of thefiberglass, and most preferably in a concentration of approximately 1 to10 (e.g., 5 to 6) percent by weight of the fiberglass.

The cured polyacetal formed in accordance with the first embodiment ispreferred over the cured polyketal of the second embodiment in view ofits enhanced stability. However, satisfactory results nevertheless areachieved when practicing the second embodiment.

The present invention provides a formaldehyde-free route to form asecurely bound formaldehyde-free fiberglass product. The bindercomposition of the present invention makes possible ease of coatingapplication, the elimination of interference by a silane, and improvedoverall economics.

The following examples are presented to provide specific examples of thepresent invention. In each instance, the thin glass plate substrate thatreceives the coating can be replaced by fiberglass. It should beunderstood, however, that the invention is not limited to the specificdetails set forth in the Examples.

EXAMPLE 1

To 44 grams of a 10 percent solution of polyvinyl alcohol in water 3.6grams of a 40 percent solution of glyoxal in water and 0.5 gram sulfuricacid catalyst were added with stirring. This liquid was coated on a thinglass plate and was heated at a temperature of 150° C. During heating apolyacetal was formed which subsequently underwent cross-linking toproduce a tough water-insoluble coating that displayed excellentadhesion to glass. Upon dynamic mechanical analysis the cured resincoating displayed a storage modulus of 165 MPa at 200° C.

EXAMPLE 2

Example 1 was repeated with the exception that 5.0 grams of sulfuricacid catalyst were provided and the coated glass plate was heated at atemperature of 200° C. Upon dynamic mechanical analysis the cured resincoating displayed a storage modulus of 150 MPa at 200° C.

EXAMPLE 3

To 88 grams of a 10 percent solution of polyvinyl alcohol in water 3.6grams of a 40 percent solution of glyoxal in water and 5.8 grams ofmaleic acid were added with stirring. This liquid was coated on a thinglass plate and was heated at a temperature of 200° C. During heating apolyacetal was formed and the maleic acid underwent reaction duringcuring to produce a tough water-insoluble coating that displayedexcellent adhesion to glass in the form of a poly(ester-acetal). Upondynamic mechanical analysis the cured resin coating displayed a storagemodulus of 170 MPa at 200° C.

EXAMPLE 4

To 2,200 grams of a 10 percent solution of polyvinyl alcohol in water36.25 grams of a 40 percent solution of glyoxal in water and 232 gramsof maleic acid were added with stirring. This liquid was coated on athin glass plate and was heated at a temperature of 200° C. Duringheating a polyacetal was formed and the maleic acid underwent reactionduring curing to produce a tough water-insoluble coating that displayedexcellent adhesion to glass in the form of a poly(ester-acetal).

EXAMPLE 5

Example 4 was repeated with the exception that 1,320 grams of the 10percent solution of polyvinyl alcohol in water, and 116 grams of maleicacid were utilized. The resulting water-insoluble poly(ester-acetal)coating displayed excellent adhesion to glass.

EXAMPLE 6

Example 4 was repeated with the exception that 880 grams of the 10percent solution of polyvinyl alcohol in water, and 58 grams of maleicanhydride were utilized. The resulting water-insolublepoly(ester-acetal) coating displayed excellent adhesion to glass.

EXAMPLE 7

Example 4 was repeated with the exception that 1,320 grams of the 10percent solution of polyvinyl alcohol in water, 72.5 grams of the 40percent solution of glyoxal in water, and 58 grams of maleic anhydridewere utilized. The resulting water-insoluble poly(ester-acetal) coatingdisplayed excellent adhesion to glass.

EXAMPLE 8

Example 4 was repeated with the exception that 145 grams of the 40percent solution of glyoxal in water, and 58 grams of maleic anhydridewere utilized. The resulting water-insoluble poly(ester-acetal) coatingdisplayed excellent adhesion to glass.

EXAMPLE 9

To 100 grams of a 10 percent solution of polyvinyl alcohol in water 0.53gram of benzaldehyde, and 0.58 gram of maleic anhydride were added withstirring. This liquid was coated on a thin glass plate and was heated ata temperature of 200° C. During heating a polyacetal was formed and themaleic acid underwent reaction during curing to produce a toughwater-insoluble coating that displayed excellent adhesion to glass inthe form of a poly(ester-acetal). Heating at 200° C. for 10 minutes wassufficient to cure the resin.

EXAMPLE 10

To 100 grams of a 10 percent solution of polyvinyl alcohol, 0.49 grammethylisobutyl ketone, and 0.58 gram of maleic acid were added withstirring and were heated at 50° C. for five minutes until uniform. Thisliquid was coated on a thin glass plate and was heated at 200° C. for 10minutes. During heating a cross-linked polyketal was formed and cured toproduce a tough water-insoluble coating that displayed excellentadhesion to glass.

EXAMPLE 11

Example 10 was repeated with the exception that 0.28 gram ofcyclohexanedione was substituted for the methylisobutyl ketone. Theresulting cross-linked polyketal coating displayed excellent adhesion toglass.

EXAMPLE 12

To 1760 g of a 10% solution of polyvinyl alcohol in water, 108.8 g of a40% solution of glyoxal was added. 1.0 g sulfuric acid was added to thissolution. The resulting solution was cured at 160° C. to produce a hardand water insoluble film with excellent adhesion to glass. Performanceof this resin was superior to those of Example 1 and Example 2.

EXAMPLE 13

Example 12 was repeated with the exception that the sulfuric acid wasreplaced with 4.0 g of aluminum sulfate. The resulting solution wascured at 160° C. to produce a hard and water insoluble film withexcellent adhesion to glass.

EXAMPLE 14

Example 13 was repeated with the exception that 72.5 g glyoxal solutionwas used. The resulting solution was cured at 160° C. to produce a hardand water insoluble film with excellent adhesion to glass.

EXAMPLE 15

Example 14 was repeated with the exception that the aluminum sulfate wasreplaced with 1.0 g of sulfuric acid. The resulting solution was curedat 160° C. to produce a hard and water insoluble film with excellentadhesion to glass.

The principles, preferred embodiments, and modes of operation of thepresent invention have been described in the foregoing specification.The invention which is protected herein, however, is not to be construedas limited to the particular forms disclosed, since these are to beregarded as illustrative rather than restrictive. Variations and changesmay be made by those skilled in the art without departing from thespirit of the invention.

1. A curable composition for use in the binding of fiberglass comprisingan acid-catalyzed reaction product of an aldehyde or ketone with amultihydric alcohol in the form of a polyacetal or polyketal which uponcuring is capable of forming a water-insoluble resin binder whichexhibits good adhesion to glass.
 2. A curable composition for use in thebinding of fiberglass according to claim 1, wherein the acid-catalyzedreaction product is formed by the reaction of an aldehyde with amultihydric alcohol and a polyacetal is formed.
 3. A curable compositionfor use in the binding of fiberglass according to claim 2, wherein saidaldehyde is a mono-aldehyde.
 4. A curable composition for use in thebinding of fiberglass according to claim 3, wherein said aldehyde is amono-aldehyde selected from the group consisting of butyraldehyde,benzaldehyde, acrolein, a copolymer of acrolein with another unsaturatedmonomer, and mixtures of the foregoing.
 5. A curable composition for usein the binding of fiberglass according to claim 2, wherein said aldehydeis a multi-aldehyde.
 6. A curable composition for use in the binding offiberglass according to claim 5, wherein said multi-aldehyde is selectedfrom the group consisting of glyoxal, glutaraldehyde, 1,5-pentanedial,1,6-hexanedial, 1,4-terephthalic dianhydride, polyarolein, and mixturesof the foregoing.
 7. A curable composition for use in the binding offiberglass according to claim 2, wherein said aldehyde is glyoxal.
 8. Acurable composition for use in the binding of fiberglass according toclaim 2, wherein said multihydric alcohol is selected from the groupconsisting of ethylene glycol, 1,2-propylene glycol, 1,3-propyleneglycol, neopentyl glycol, pentaerythrytol, glucose, sorbitol, polyvinylalcohol, ethylene vinyl alcohol copolymer, and mixtures of theforegoing.
 9. A curable composition for use in the binding of fiberglassaccording to claim 2, wherein said multihydric alcohol is polyvinylalcohol.
 10. A curable composition for use in the binding of fiberglassaccording to claim 2, wherein the catalyst utilized to achieveacid-catalysis during the formation of the polyacetal is selected fromthe group consisting of maleic acid, maleic anhydride, succinic acid,succinic anhydride, and oxalic acid and is capable of undergoingreaction to form a poly(ester-acetal) during curing.
 11. A curablecomposition for use in the binding of fiberglass according to claim 2wherein the catalyst utilized to achieve acid-catalysis during theformation of said polyacetal is maleic acid and is capable of undergoingreaction to form a poly(ester-acetal) during curing.
 12. A curablecomposition for use in the binding of fiberglass according to claim 2,wherein said catalyst utilized to achieve acid-catalysis during theformation of the polyacetal is selected from the group consisting ofsulfuric acid, sulfate salts, bisulfite, nitrate, and nitric acid.
 13. Acurable composition for use in the binding of fiberglass according toclaim 1, wherein that acid-catalyzed reaction product is formed by thereaction of a ketone with a multihydric alcohol and a polyketal isformed.
 14. A curable composition for use in the binding of fiberglassaccording to claim 13, wherein said ketone is selected from the groupconsisting of methylethyl ketone, methylisobutyl ketone, acetoquinone,cyclohexanedione, acetylacetone, benzophenone, polyketones, and mixturesof the foregoing.
 15. A curable composition for use in the binding offiberglass according to claim 13, wherein said ketone is methylisobutylketone.
 16. A curable composition for use in the binding of fiberglassaccording to claim 13, wherein said ketone is cyclohexanedione.
 17. Acurable composition for use in the binding of fiberglass according toclaim 13, wherein said multihydric alcohol is selected from the groupconsisting of ethylene glycol, 1,2-propylene glycol, 1,3-propyleneglycol, neopentyl glycol, pentaerythrytol, glucose, sorbitol, polyvinylalcohol, ethylene vinyl alcohol copolymer, and mixtures of theforegoing.
 18. A curable composition for use in the binding offiberglass according to claim 13, wherein said multihydric alcohol ispolyvinyl alcohol.
 19. A curable composition for use in the binding offiberglass according to claim 13, wherein said catalyst introduced toachieve acid-catalysis during the formation of said polyketal isselected from the group consisting of maleic acid maleic anhydride,succinic acid, and succinic anhydride.
 20. A curable composition for usein the binding of fiberglass according to claim 13, wherein saidcatalyst introduced to achieve acid-catalysis during the formation ofsaid polyketal is maleic acid.
 21. A process for binding fiberglasscomprising providing on said fiberglass a coating of a compositioncomprising an acid-catalyzed reaction product of an aldehyde or ketonewith a multihydric alcohol in the form of a polyacetal or polyketal, andthereafter curing said composition while present as a coating on saidfiberglass to form a water-insoluble resin binder which exhibits goodadhesion to glass.
 22. A process for binding fiberglass according toclaim 21, wherein said reaction product is a polypolyacetal formed by analdehyde and a multihydric alcohol.
 23. A process for binding fiberglassaccording to claim 22, wherein said aldehyde is a mono-aldehyde.
 24. Aprocess for binding fiberglass according to claim 23, wherein saidmono-aldehyde selected from the group consisting of butyraldehyde,benzaldehyde, acrolein, a copolymer of acrolein with another unsaturatedmonomer, and mixtures of the foregoing.
 25. A process for bindingfiberglass according to claim 23, wherein said aldehyde is amulti-aldehyde.
 26. A process for the binding fiberglass according toclaim 25, wherein said multi-aldehyde is selected from the groupconsisting of glyoxal, glutaraldehyde, 1,5-pentanedial, 1,6-hexanedial,1,4-terephthalic dianhydride, polyarolein, and mixtures of theforegoing.
 27. A process for the binding of fiberglass according toclaim 22, wherein said aldehyde is glyoxal.
 28. A process for thebinding of fiberglass according to claim 22, wherein said multihydricalcohol is selected from the group consisting of ethylene glycol,1,2-propylene glycol, 1,3-propylene glycol, neopentyl glycol,pentaerythrytol, glucose, sorbitol, polyvinyl alcohol, ethylene vinylalcohol copolymer, and mixtures of the foregoing.
 29. A process for thebinding of fiberglass according to claim 22, wherein said multihydricalcohol is polyvinyl alcohol.
 30. A process for the binding offiberglass according to claim 22, wherein the catalyst utilized toachieve acid-catalysis during the formation of the polyacetal isselected from the group consisting of maleic acid, maleic anhydride,succinic acid, and succinic anhydride, and during said curing apoly(ester-acetal) is formed.
 31. A process for the binding offiberglass according to claim 22, wherein the catalyst utilized toachieve acid-catalysis during the formation of the polyacetal is maleicacid, and during said curing a poly(ester-acetal) is formed.
 32. Aprocess for binding fiberglass according to claim 22, wherein saidreaction product is a polyketal formed by a ketone and a multihydricalcohol.
 33. A process for binding fiberglass according to claim 32,wherein said ketone is selected from the group consisting of methylethylketone, methylisobutyl ketone, acetoquinone, cyclohexanedione,acetylacetone, benzophenone, polyketones, and mixtures of the foregoing.34. A process for binding fiberglass according to claim 32, wherein saidketone is methylisobutyl ketone.
 35. A process for binding fiberglassaccording to claim 32, wherein said ketone is cyclohexanedione.
 36. Aprocess for binding fiberglass according to claim 32, wherein saidmultihydric alcohol is selected from the group consisting of ethyleneglycol, 1,2-propylene glycol, 1,3-propylene glycol, neopentyl glycol,pentaerythrytol, glucose, sorbitol, polyvinyl alcohol, ethylene vinylalcohol copolymer, and mixtures of the foregoing.
 37. A process forbinding fiberglass according to claim 32, wherein said multihydricalcohol is polyvinyl alcohol.
 38. A process for the binding offiberglass according to claim 32, wherein the catalyst utilized toachieve acid-catalysis during the formation of the polyketal is selectedfrom the group consisting of maleic anhydride, succinic acid, andsuccinic anhydride.
 39. A process for the binding of fiberglassaccording to claim 32, wherein the catalyst utilized to achieveacid-catalysis is maleic anhydride.
 40. A curable composition for thebinding of fiberglass according to claim 1, further comprising at leastone component selected from the group consisting of adhesion promoters,oxygen scavengers, moisture repellents, solvents, emulsifiers, pigments,fillers, anti-migration aids, coalescents, wetting agents, biocides,plasticizers, organosilanes, anti-foaming agents, colorants, waxes,suspending agents, anti-oxidants, and crosslinking catalysts.
 41. Aformaldehyde-free fiberglass product formed by the process of claim 22.42. A formaldehyde-free fiberglass product formed by the process ofclaim
 30. 43. A formaldehyde-free fiberglass product formed by theprocess of claim
 32. 44. A fiberglass product according to claim 41wherein the product is building insulation.
 45. A fiberglass productaccording to claim 30 wherein the product is building insulation.
 46. Afiberglass product according to claim 32 wherein the product is buildinginsulation.
 47. A fiberglass product formed by the process of claim 22,wherein the product is a microglass-based substrate useful for any of aprinted circuit board, battery separator, filter stock, or reinforcementscrim.
 48. A fiberglass product formed by the process of claim 30,wherein the product is a microglass-based substrate useful for any of aprinted circuit board, battery separator, filter stock, or reinforcementscrim.
 49. A fiberglass product formed by the process of claim 32wherein the product is a microglass-based substrate useful for any of aprinted circuit board, battery separator, filter stock, or reinforcementscrim.
 50. A formaldehyde-free fiberglass product formed by the processof claim 32.